Intsimbi engatyiwa (Stainless Steel)sisishunqulelo sentsimbi engena acid-resistant, kwaye amabakala entsimbi amelana nemithombo yeendaba ezonakalisayo ebuthathaka njengomoya, umphunga, amanzi, okanye aneempawu ezingenasici zibizwa ngokuba yintsimbi engatyiwayo.
Igama elithile "yenziwe ngentsimbi eshayinayo" ayibhekiseli nje kuhlobo olunye lwensimbi engenasici, kodwa ibhekiselele kwiintlobo ezingaphezu kwekhulu zensimbi engenasici kwimizi-mveliso, nganye inentsebenzo entle kwindawo yayo yesicelo.
Zonke ziqulethe i-17 ukuya kwi-22% ye-chromium, kwaye amabakala ensimbi angcono aqulethe i-nickel.Ukongeza i-molybdenum kunokuphucula ngakumbi i-atmospheric corrosion, ngakumbi ukuxhathisa kwi-corrosion kwi-atmospheres ene-chloride.
一.Ulwahlulo lwensimbi engenasici
1. Yintoni insimbi engenasici kunye ne-asidi-resistant steel?
Impendulo: Intsimbi estainless sisishunqulelo sentsimbi engena acid-resistant, ekwaziyo ukumelana nemithombo yeendaba eyonakalisayo enjengomoya, umphunga, amanzi, okanye inentsimbi engatyiwayo.Imigangatho yentsimbi egqwethiweyo ibizwa ngokuba ziintsimbi ezixhathisa i-asidi.
Ngenxa yomahluko ekubunjweni kweekhemikhali kwezi zimbini, ukuxhathisa kwe-corrosion kuyahluka.Intsimbi eqhelekileyo engatyiwa sisiqhelo ayixhathisi kumhlwa okuphakathi kwemichiza, lo gama intsimbi enganyangekiyo ngeasidi iyonke ayinasilima.
2. Indlela yokwahlula intsimbi engenasici?
Impendulo: Ngokwemeko yombutho, inokwahlulwa ibe yintsimbi ye-martensitic, insimbi ye-ferritic, i-austenitic steel, i-austenitic-ferritic (i-duplex) yensimbi engenasici kunye ne-precipitation iqinisa insimbi engenasici.
(1) Intsimbi ye-Martensitic: amandla aphezulu, kodwa iplastiki engalunganga kunye ne-weldability.
Amanqanaba asetyenziswa ngokuqhelekileyo ensimbi engenasici ye-martensitic yi-1Cr13, 3Cr13, njl., ngenxa yomxholo wekhabhoni ephezulu, inamandla amakhulu, ukuqina kunye nokumelana nokunxiba, kodwa ukuxhathisa ukubola kumbi kancinane, kwaye isetyenziselwa iipropathi eziphezulu zoomatshini kunye. ukumelana nomhlwa.Ezinye iindawo ngokubanzi ziyafuneka, njengemithombo, iiblade ze-injini yomphunga, iivalvu zokucinezela ngoxinzelelo lwehydraulic, njl.
Olu hlobo lwentsimbi lusetyenziswa emva kokucima kunye nokufudumala, kwaye i-annealing iyadingeka emva kokubumba kunye nokunyathela.
(2) Intsimbi ye-Ferritic: 15% ukuya kwi-30% yechromium.Ukuxhatshazwa kwayo kwe-corrosion, ukuqina kunye nokunyuka kwe-weldability kunye nokunyuka komxholo we-chromium, kunye nokuchasana kwayo ne-chloride stress corrosion kungcono kunezinye iintlobo zensimbi engenasici, ezifana ne-Crl7, i-Cr17Mo2Ti, i-Cr25, i-Cr25Mo3Ti, i-Cr28, njl.
Ngenxa yomxholo wayo ophezulu wechromium, ukuxhathisa ukubola kunye nokumelana ne-oxidation kulungile, kodwa iipropathi zayo zomatshini kunye nepropathi yenkqubo ihlwempuzekile.Isetyenziswa kakhulu kwizakhiwo ezinokumelana ne-asidi kunye noxinzelelo oluncinci kunye nentsimbi ye-anti-oxidation.
Olu hlobo lwentsimbi lunokuxhathisa ukubola kwe-atmosfera, i-nitric acid kunye nesisombululo setyuwa, kwaye ineempawu zokumelana nokushisa okuphezulu kwe-oxidation kunye ne-coefficient encinci yokwandisa i-thermal.Isetyenziswe kwi-asidi ye-nitric kunye nezixhobo zefektri yokutya, kwaye ingasetyenziselwa ukwenza iindawo ezisebenza kumaqondo okushisa aphezulu, njengeendawo ze-turbine yegesi, njl.
(3) Intsimbi ye-Austenitic: Iqulethe ngaphezu kwe-18% ye-chromium, kwaye iqulethe malunga ne-8% ye-nickel kunye nenani elincinci le-molybdenum, i-titanium, i-nitrogen kunye nezinye izinto.Ukusebenza kakuhle kukonke, ukumelana nokubola ngamajelo ohlukeneyo eendaba.
Ngokuqhelekileyo, unyango lwesisombululo luyamkelwa, oko kukuthi, intsimbi ishushu kwi-1050-1150 ° C, kwaye emva koko ipholile ngamanzi okanye i-air-cooled ukuze ifumane isakhiwo se-austenite sesigaba esisodwa.
(4) I-Austenitic-ferritic (i-duplex) yensimbi engenasici: Ineenzuzo zentsimbi ye-austenitic kunye ne-ferritic, kwaye ine-superplasticity.I-Austenite kunye ne-ferrite nganye i-akhawunti malunga nesiqingatha sensimbi engenasici.
Kwimeko yomxholo we-C ophantsi, umxholo we-Cr yi-18% ukuya kwi-28%, kwaye umxholo we-Ni yi-3% ukuya kwi-10%.Ezinye iintsimbi zikwaqulathe izinto zokuhlanganisa ezifana neMo, Cu, Si, Nb, Ti, kunye neN.
Olu hlobo lwensimbi luneempawu ze-austenitic kunye ne-ferritic stainless steels.Xa kuthelekiswa ne-ferrite, ineplastiki ephezulu kunye nokuqina, akukho brittleness yokushisa kwegumbi, iphucule kakhulu ukuxhathisa kwe-intergranular corrosion kunye nokusebenza kwe-welding, ngelixa igcina intsimbi Umzimba wensimbi engenasici u-brittle kwi-475 ° C, une-conductivity ephezulu ye-thermal, kwaye uneempawu ze-superplasticity. .
Xa kuthelekiswa ne-austenitic steel stainless, inamandla aphezulu kwaye iphucule kakhulu ukuxhathisa kwi-intergranular corrosion kunye ne-chloride stress corrosion.I-Duplex steel stainless steel ine-pitting corrosion resistance encomekayo kwaye ikwayintsimbi egcina i-nickel.
(5) Imvula iqinisa insimbi engenasici: i-matrix yi-austenite okanye i-martensite, kunye nemigangatho esetyenziswa ngokuqhelekileyo ye-precipitation i-stainless steel stainless yi-04Cr13Ni8Mo2Al njalo njalo.Yinsimbi engenasici enokuthi iqiniswe (iqiniswe) ngokuqiniswa kwemvula (eyaziwa nangokuthi iminyaka yobudala).
Ngokokwakheka, yahlulwe yaba yintsimbi ye-chromium, i-chromium-nickel yensimbi engenasici kunye ne-chromium manganese nitrogen intsimbi.
(1) I-Chromium insimbi engagqwaliyo inokumelana ne-corrosion ethile (i-asidi ene-oxidizing, i-asidi ye-organic, i-cavitation), ukumelana nobushushu kunye nokumelana nokunxiba, kwaye isetyenziswa ngokubanzi njengezixhobo zezixhobo zezikhululo zamandla, iikhemikhali kunye ne-petroleum.Nangona kunjalo, i-weldability yayo imbi, kwaye ingqalelo kufuneka ihlawulwe kwinkqubo ye-welding kunye neemeko zonyango lobushushu.
(2) Ngexesha le-welding, i-chromium-nickel steel stainless steel iphantsi kokufudumala ngokuphindaphindiweyo kwi-carbides ye-precipitate, eya kunciphisa ukuxhathisa kwe-corrosion kunye neempawu zomatshini.
(3) Amandla, i-ductility, ukuqina, ukubumbeka, ukuwelda, ukuxhathisa ukunxiba kunye nokuxhathisa ukubola kwe-chromium-manganese yensimbi engenasici ilungile.